N. Mizuno, Keigo Kamata
Oct 1, 2011
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Influential Citations
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Journal
Coordination Chemistry Reviews
Abstract
Abstract Vanadium compounds have attracted much attention because they have widely been used for homogeneous, heterogeneous, industrial, and biological oxidation processes with alkyl hydroperoxides, H 2 O 2 , and O 2 . The present review summarizes recent developments for homogeneous and heterogeneous liquid-phase oxidation of hydrocarbons with H 2 O 2 catalyzed by vanadium complexes and vanadium-based polyoxometalates including our recent studies on selective oxidation of hydrocarbons with H 2 O 2 catalyzed by divanadium-substituted polyoxotungstates, [γ-SiW 10 O 36 V 2 ( μ -OH) 2 ] 4− ( I ) and [γ-PW 10 O 36 V 2 ( μ -OH) 2 ] 3− ( II ).