A. Constable, W. McDonald, Lynne C. Sawkins
1978
Citations
0
Influential Citations
59
Citations
Journal
Journal of The Chemical Society, Chemical Communications
Abstract
The oxime of isopropyl phenyl ketone (Z-isomer) with NaOAc–Na2PdCl4 gives [Pd3(ONCPriPh)6] and whereas pinacolone oxime carbopalladates regiospecifically on the t-butyl group, the dimethylhydrazone carbopalladates only on the methyl group: acetone oxime O-allyl ether palladates on the central carbon atom of the allyl group with nucleophilic attack (e.g. by OMe–) on the terminal carbon atom.