R. A. Khisamutdinov, O. V. Shitikova, G. R. Anpilogova
May 28, 2015
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Journal
Russian Journal of Inorganic Chemistry
Abstract
Palladium(II) chloro complexes with (RS)-1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-tria-zol-1-ylmethyl)pentan-3-ol (L), such as trans-[PdCl2L2], cis-[PdCl2L2], and trans-[Pd2(μ-Cl)2Cl2L2], were synthesized. The structures of their coordination cores and the coordination modes of the reagent to the metal ion via the N(4) atom of the triazole ring were established by electronic, IR, and 1H and 13C NMR spectroscopy. The ratio of RS- and RR(SS)-diastereomers in the complexes was determined from the complete assignment of signals in their 1H and 13C NMR spectra.