L. Ray, and Mobin M. Shaikh, P. Ghosh
Jan 9, 2007
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Organometallics
Abstract
Synthetic and structural studies of Pd(II) and Au(I) complexes of a new O-functionalized N-heterocyclic carbene ligand, namely, 1-(o-methoxybenzyl)-3-tert-butylimidazol-2-ylidene, are reported. Specifically, the N-heterocyclic carbene precursor 1-(o-methoxybenzyl)-3-tert-butylimidazolium bromide (1a) was synthesized by the reaction of 2-methoxybenzyl bromide and tert-butylimidazole in 44% yield. The Au(I) and Pd(II) complexes [1-(o-methoxybenzyl)-3-tert-butylimidazol-2-ylidene]AuCl (1c) and [1-(o-methoxybenzyl)-3-tert-butylimidazol-2-ylidene]2PdCl2 (1d) were prepared in 77% and 89% yields, respectively, by the commonly used silver carbene transfer route from the silver complex {[1-(o-methoxybenzyl)-3-tert-butylimidazol-2-ylidene]2Ag}+Br- (1b). The silver complex 1b was in turn synthesized from the reaction of 1a with Ag2O. The molecular structures of the complexes 1c and 1d have been determined by X-ray diffraction studies, which revealed that the gold complex 1c possessed a linear geometry while the pall...