Asen Kolev, M. Skumov, E. Balbolov
Mar 1, 2003
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Journal
Reaction Kinetics and Catalysis Letters
Abstract
The acetoxylation of cyclododecene by palladium(II) acetate, hydroquinone and iron(II) phthalocyanine (FePc) was studied at 0.1 ÷ 1.0 MPa dioxygen pressure and temperature range of 313 to 335 K. Cyclododec-2-en-1-yl acetates in high selectivity (93.4%) at a conversion of cyclododecene up to 93.8% were obtained. The kinetic model assumed the significant inhibition effect of the allyl acetates.