J. Lipkowski, K. S. Andronati, Y. Simonov
2005
Citations
0
Influential Citations
4
Citations
Journal
Journal of Structural Chemistry
Abstract
Abstract5-Phenyl-1-methyl-7-bromo-3-hydroxy-1,2-dihydro-3H-1,4-benzodiazepin-2-one and its 5-(o-chloro)-phenyl analog form 2:1 (host:guest) inclusion compounds with benzene. The crystal structures of the compounds were studied by the single-crystal XRD method and were interpreted as host (H) (benzodiazepine) — guest (G) (benzene solvent molecule) complexes. The studied structures, revealing H-H and H-G interactions as both typical hydrogen bonds and π-π, C-H⋯π weak interactions, may serve as models for ligand-receptor binding.