D. M. Roe, A. Massey
Jul 1, 1970
Citations
0
Influential Citations
23
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Decomposing “(pentafluorophenyl)magnesium bromide” in dioxane provides a convenient system for generating tetrafluorobenzyne in the presence of transition metal complexes. Four benzyne “adducts”, C 5 H 5 NiC 5 H 5 C 6 F 4 (two isomers), Co 4 (CO) 10 C 6 F 4 and Fe 2 (CO) 8 C 6 F 4 , have been isolated during the initial survey of this highly promising synthetic technique.