A. Y. Wu, E. Whalley
1979
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0
Influential Citations
2
Citations
Journal
Journal of Chemical Physics
Abstract
The phase diagram of antimony pentachloride has been measured in the range −60–160 °C and 0–43 kbar to test the suggestion that the molecular solid ought to transform to an ionic solid, such as SbCl4+SbCl6− or SbCl4+Cl−, under pressure. In the experimental pressure range, it does not. The equilibrium lines for the L–I, L–II, and I–II transitions and their volume and entropy changes were determined.