D. Seyferth, G. J. Murphy
May 16, 1973
Citations
0
Influential Citations
9
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The reaction of phenylmercuric chloride, 1-bromo-2,2,2-tetrafluoroethane and methanolic sodium methoxide in THF at −35° gave PhHgCFBrCF 3 in good yield. Thermolysis of this mercurial at 155° for 24 h in the presence of olefins gave gem -fluoro(trifluoromethyl)cyclopropanes, while its reaction with triethylsilane produced Et 3 SiCHFCF 3 .