E. P. Serebryakov, G. K. Nalbandyan, S. Vartanyan
Jul 1, 1986
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Journal
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
Abstract
Conclusions1.The photolysis of 2,2-dimethyltetrahydropyran-4-one in methanol in the presence of an equimolar amount of TiCl4 leads to the formation of stereoisomer 2,5-di(3',3'-dimethyl) 4'-oxacyclohexano)dioxolanes.2.In the absence of TiCl4, the irradiation of 2,2-dimethyltetrahydropyran-4-one in methanol leads to 4-hydroxymethyl-2,2-dimethyltetrahydropyran-4-ol and 2,2-dimethyltetra-hydropyran-4-ol.