D. Gray, D. Phillips
Apr 15, 1973
Citations
0
Influential Citations
4
Citations
Journal
Journal of Chemical Physics
Abstract
The vapor of 1,3‐bis(trifluoromethyl) benzene excited near the 0–0 transition of the first absorption band has been shown to fluoresce with a quantum efficiency of 0.145, and intersystem cross to the triplet manifold with a quantum yield of 0.83. At shorter wavelengths, other competing processes occur. Rate parameters for quenching of the excited singlet state of 1,3‐bis(trifluoromethyl) benzene by O2 and various olefins are tabulated.