H. Martin, R. Iden, H. Landen
1986
Citations
0
Influential Citations
10
Citations
Journal
Journal of Electron Spectroscopy and Related Phenomena
Abstract
Abstract The He(I)α photoelectron spectra and electron transmission spectra of thietane 1,1-dioxide, thiete. 1,1-dioxide and related four-membered ring sulfones have been measured. The comparison with halogenated derivatives allows unambiguous assignment of the π ionization and π ★ attachment processes which are the most important levels from a chemical viewpoint. The strongly stabilizing inductive effect of the sulfone group—origin of the high reactivity of thiete 1,1-dioxide — is clearly disclosed in both PE and ET spectra.