M. Barwick, Tareq Abu-Izneid, I. Novák
Jul 20, 2008
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Journal
Chemical Physics Letters
Abstract
Abstract The electronic structures of bis(pentafluorophenyl)zinc ( I ) and dichloro( N , N , N ′, N ′-tetramethylethylenediamine)zinc(II) ( II ) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and DFT/OVGF calculations. We discuss the properties of Zn-aryl and Zn–N bonds on the basis of spectroscopic evidence i.e. the nature of metal–ligand bonding. Our study is the first reported one on the photoelectron spectra of zinc-aryl complex.