Yin Jingmei
2011
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Journal
Journal of University of Science and Technology Liaoning
Abstract
The photopromoted carbonylation of dihaloalkanes with methyl formate catalyzed by cobalt and copper salts catalysts is studied under ambient conditions.The results indicate that the single carbonylations of 1,6-dibromohexane and 1-bromo-6-chlorohexane occurred.The corresponding monocarbonylated products Br(CH2)6CO2CH3 and Cl(CH2)6CO2CH3 are obtained.