A. Boulkamh, D. Harakat, T. Sehili
Dec 1, 2001
Citations
0
Influential Citations
10
Citations
Journal
Pest management science
Abstract
UV irradiation of metoxuron in aerated aqueous solution at 254 nm or between 300 and 450 nm led initially to an almost specific photohydrolysis of the C-Cl bond, resulting in the formation of 3-(3-hydroxy-4-methoxyphenyl)-1,1-dimethylurea (MX3) and hydrogen chloride. The quantum yield was determined to be 0.020 (+/- 0.005) in solutions irradiated at 254 nm. Five minor photoproducts were also identified, in particular the dihydroxydimethoxybiphenyl derivatives resulting from the phototransformation of MX3. Irradiation increased the toxicity of an aqueous solution of metoxuron to the marine bacterium Vibrio fischeri.