O. Kajimoto, T. Nayuki, T. Kobayashi
Jul 9, 1993
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0
Influential Citations
19
Citations
Journal
Chemical Physics Letters
Abstract
The rate of formation of the intramolecular charge-transfer state of 4- (N,N-dimethylamino) benzonitrile (DMABN) has been determined in supercritical CF3H using a fast single-photon counting technique. The rate constant increases rapidly with increasing CF3H density, indicating the importance of the polar environment which is brought about by the CF3H molecules clustering around DMABN.