F. Yamashita, H. Kuniyasu, J. Terao
Jan 3, 2008
Citations
0
Influential Citations
60
Citations
Journal
Organic letters
Abstract
Unsymmetrical internal alkynes such as ethyl phenylpropiolate (2b) successfully underwent Pt-catalyzed decarbonylative arylthiolation by thioesters. The regio- and stereoselective insertion of 2b into an S-Pt bond was confirmed by reaction with a platinum complex with an S-Pt-Cl framework.