V. Kukushkin, V. K. Bel'skii, E. Aleksandrova
Sep 1, 1992
Citations
0
Influential Citations
30
Citations
Journal
Inorganic Chemistry
Abstract
The complex cis-[Pt(Me 2 C=NOH) 2 Cl 2 ], 1, isomerizes into trans- [Pt(Me 2 C=NOH) 2 Cl 2 ], 2, upon heating in the solid phase at 140 o C. Isomerization of 1 into 2 was also performed in acetonitrile or acetone solutions, containing catalytic amounts of Me 2 C=NOH; in the DMF-DMSO mixture, a 2-propanone oxime is displaced by DMSO in formation of cis-, 3, and trans-[Pt(Me 2 C=NOH) (DMSO)Cl 2 ].