E. Laviron, J. Besancon, F. Huq
Oct 17, 1978
Citations
0
Influential Citations
21
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Titanocene dichloride, Cp2TiCl2, cyclopentadienyltitanium trichloride, CpTiCl3, and compounds of the type Cp2Ti(Cl)OAr, Cp2Ti(OAr)(OAr′). CpTi(OAr)3 (Ar, Ar′, substituted benzene rings) have been investigated polarographically and by linear potential sweep voltammetry in dimethyl-formamide. Cp2TiCl2 shows a third wave, which had not been hitherto reported, at very negative potentials. The reduction mechanism of the different compounds is examined in detail.