Xiaobo Huang, J. Meng, Yu Dong
Jun 24, 2010
Citations
0
Influential Citations
68
Citations
Journal
Polymer
Abstract
Abstract The polymer could be obtained by the polymerization of 1,4-dibutoxy-2,5-diethynylbenzene (M-1) with 1,4-diazidobenzene ( M-2) via click reaction. The polymer show blue fluorescence. The responsive optical properties of the polymer on various transition metal ions were investigated by fluorescence spectra. Compared with other cations, such as Co 2+ , Ni 2+ , Ag + , Cd 2+ , Cu 2+ and Zn 2+ , Hg 2+ can exhibit the most pronounced fluorescence response of the polymer Hg 2+ can exhibit the most pronounced fluorescence response of the polymer due to triazole moiety in the polymer main chain as the metal binding ligand. The results indicate this kind of conjugated polymer with triazole moiety synthesized by click reaction can be used as a selective fluorescence sensor for Hg 2+ detection.