G. Meunier, P. Hémery, S. Boileau
Jun 1, 1982
Citations
0
Influential Citations
10
Citations
Journal
Polymer
Abstract
Abstract The free-radical polymerization of vinyl chloroformate and of some of its derivatives, e.g., vinyl carbamates and vinyl carbonates, has been studied. Peroxydicarbonates are the most convenient initiators, especially for vinyl chloroformate polymerization carried out in bulk and in methylene chloride solution at 35°C since they lead to high molecular-weight polymers and quantitative yields. The structure of these polymers has been examined by i.r., 1 H and 13 C n.m.r. spectroscopy.