A. Tatehata, S. Natsume
May 1, 1984
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0
Influential Citations
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Journal
Bulletin of the Chemical Society of Japan
Abstract
Four diastereoisomers of the type [Co(S- or (R-pn)(phen)2]3+ (pn=1,2-propanediamine; phen=1,10-phenanthroline) were prepared and characterized by absorption, circular dichroism (CD), and 1H NMR spectra. High stereoselectivity in the formation of the diastereoisomers was observed and the Λ-isomer of [Co(S-pn)(phen)2]3+ was formed in preference to the Δ-isomer.