A. M. Sipyagin, C. P. Bateman, Ying-Teck Tan
Dec 28, 2001
Citations
0
Influential Citations
35
Citations
Journal
Journal of Fluorine Chemistry
Abstract
Abstract The preparation of the first ortho -substituted pentafluorosulfanylbenzenes was achieved. Oxidative fluorination (AgF 2 ) of a series of aromatic disulfides containing different substituents ortho to the disulfide moiety gave only one ortho -substituted SF 5 -benzene, namely 1-fluoro-4-nitro-2-pentafluorosulfanylbenzene. This compound has been transformed into a variety of other ortho -substituted SF 5 -benzenes by nucleophilic substitution reactions.