J. Thibonnet, P. Knochel
Apr 29, 2000
Citations
0
Influential Citations
33
Citations
Journal
Tetrahedron Letters
Abstract
Abstract α-Bromonitriles, such as 1 , 2 or the α-bromosulfone 3 , undergo a smooth bromine–magnesium exchange with isopropylmagnesium bromide furnishing new functionalized organomagnesium species which react smoothly with various electrophiles like Me 3 SiCl, Bu 3 SnCl, allyl bromides, aldehydes, ketones or acid chlorides providing the expected products of type 7 , 8 or 9 .