H. Frohn, M. Giesen, A. Klose
Jan 11, 1996
Citations
0
Influential Citations
28
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Pentafluorophenyl(fluoro)silanes (C 6 F 5 ) n SiF 4−n (n = 1, 2) were prepared from the corresponding ethoxysilanes by sequential chlorodeethoxylation with SOCl 2 and fluoridation of chlorosilanes with SbF 3 . The conversion of C 6 F 5 Si(OEt) 3 and C 6 F 5 SiCl 3 into C 6 F 5 SiF 3 with anhydrous HF was described. Some reactions of C 6 F 5 SiF 3 with electrophiles and nucleophiles were studied.