Simon T. Clausing, Daniel Morales Salazar, A. Orthaber
Aug 20, 2020
Citations
0
Influential Citations
4
Citations
Journal
Inorganica Chimica Acta
Abstract
Abstract A 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) functionalized phosphaalkene was used as a bidentate ligand towards a [Cu(I)L2]+ complex. The spectroscopic, electrochemical and photophysical properties of the compound were studied revealing a rich redox chemistry indicative of ligand non-innocence. The compound is weakly emissive with excited state lifetimes of up to 9 ns. NMR and electrochemical analysis indicate a complex dynamic behavior of this photosensitizer in solution.