Kodjo Charles Guillaume, Kangah Niameke Jean-Baptiste, Kablan Ahmont Landry Claude
2017
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Abstract
The compound N, N'-Bis(3-nitrophenylmethylene)cyclohexane-1,2-diamine (α-diimine Shiff base) was synthesized and characterized by MS, IR, NMR H and X-ray single crystal analysis. While the cyclohexane-1,2-diamine used for the synthesis of this composite is a racemic cis and trans mixture, we observed by x-ray diffraction for the product N,N'-bis(3nitrophenylmethylene) cyclohexane-1,2-diamine only the (1R,2R)trans enantiopure. The crystalline network cohesion of this compound is assured by a combination of C-HO and C-HN hydrogen bonds. It crystallizes in the monoclinic non-standard I2/a space group.