A. Endo, K. Shimizu, Gen P. Satô
May 5, 1985
Citations
0
Influential Citations
8
Citations
Journal
Chemistry Letters
Abstract
Four tris(3-substituted acetylacetonato)ruthenium(III) complexes were newly synthesized and their electrochemical oxidation and reduction were investigated in acetonitrile. The oxidation and reduction potentials of [RuIII(R′-CO-CR-CO-R″)-] can be expressed as a linear function of the sum of the Hammett constants, if one uses the para-position value for R and the meta-position values for R′ and R″.