M. Itoh, Iwata Kenji, Mineo Kobayashi
Nov 15, 1999
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Journal
Journal of Organometallic Chemistry
Abstract
Abstract Vinylsilane (CH2CHSiH3) was prepared by the dehydrochlorination reaction between SiH4 and vinyl chloride. The reactions were carried out in the gas phase at 450–500°C using a tube reactor, and the maximum yield of vinylsilane was 21% when the conversion of SiH4 was 32%. A small amount of CCl4 and CH3NO2 accelerated the reaction. A reaction mechanism involving :SiH2, which was generated by the thermal decomposition of SiH4, was proposed.