Helmut Duddecka, N. A. McKervey, D. Rosenbauma
1990
Citations
0
Influential Citations
3
Citations
Journal
Tetrahedron Letters
Abstract
Abstract The hydriodic-acid-catalyzed rearrangement of di-tert.-butyladamantanol (1) afforded iodo-di-tert.-butyl protoadamantane (2). A threestep rearrangement sequence is proposed. The 1H and 13C NMR signals of the tert.-butyl groups in 2 show coalescence effects at different temperatures indicating atropisomerism.