F. Elytle, L. M. Petrosky, L. Carlson
Dec 1, 1971
Citations
0
Influential Citations
50
Citations
Journal
Analytica Chimica Acta
Abstract
Abstract The p.m.r. spectra of 2,2′-bipyridine, tris(2,2′-bipyridine)ruthenium(II) dichloride, dichloro-bis(2,2′-bipyridine)ruthenium(II), ethylenediamine-bis(2,2′-bipyridine)ruthenium(II)dichloride, 2,2′,2″-terpyridine,bis(2,2′,2″-terpyridine)ruthenium-(II) diiodide and bis(2,2′,2″terpyridine)osmium(II) dichloride have been reported and analyzed. From the p.m.r. data, the symmetry of the complex and the geometry of the ligand within the complex are predicted. In some cases, attempts to explain anomalous luminescence behavior are made on the basis of the structural analysis.