Bruno Princet, Helene Gardes‐Gariglio, J. Pornet
Jun 16, 2000
Citations
0
Influential Citations
10
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The 3,3-bis(trimethylsilyl)propene reacts with iminium ions generated in situ from secondary amines by an aminomethylation–desilylation process, leading to ( E )-β-aminovinylsilanes. When a secondary amine with two secondary groups is used, the reaction fails, the steric hindrance probably inhibiting the reaction.