S. Nesterov, Savaş Küçükyavuz, A. Önal
Jun 1, 1999
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Influential Citations
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Journal
Journal of Radioanalytical and Nuclear Chemistry
Abstract
Radiation induced chain addition of allylbenzene to 1,4-dioxane has been studied by IR-, UV-, mass-, NMR- and ESR-spectrometry. Efficiency of the addition depends on the concentration of monomer and it has an optimum atCmonom<0.125M. Apparently, upper concentration limit of the reaction is caused by absorbed energy transfer on the molecule, of monomer followed by energy deactivation. Radiation-chemical yields of the product are 12 and 31 molec./100 eV for 0.125M and 0.07M solution, respectively. The value ofGprod. is an evidence of chain character of the process.