A. B. Terent’ev, R. Freĭdlina
Oct 1, 1966
Citations
0
Influential Citations
1
Citations
Journal
Russian Chemical Bulletin
Abstract
1. In the telomerization of ethylene by methyl formate in the presence of peroxide, together with the methyl esters of acids of normal structure, the methyl ester of α-ethyloenanthic acid and the propyl ester of propionic acid are produced. 2. A mechanism was proposed for the formation of these esters, including the rearrangement of radicals with 1,6- and 1,5-migration of the hydrogen atoms, respectively.