H. Bock, W. Schulz, U. Stein
Jul 1, 1981
Citations
0
Influential Citations
13
Citations
Journal
Chemische Berichte
Abstract
Radical Ions, 47. Note on the Structural Change during the One-Electron Oxidation of Bis(dimethylamino) Disulfide On one-electron oxidation, (H3C)2NSSN(CH3)2 considerably changes its structure: where as the neutral molecule according to the ionization band pattern of the PE spectrum displays N and S lone pairs perpendicular to each other, as ESR spectroscopic comparison suggests a planarized skeleton for the radical cation. INDO closed and open shell total energy hypersurfaces for the model compounds H2NSSNH2 and support the discussion of the spectra.