A. Birch, D. Bogsányi, L. Kelly
Jul 14, 1981
Citations
0
Influential Citations
9
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Summary The rates of reaction of pentane-2,4-dione with a range of η 5 -tricarbonylcyclohexadienyliron cation salts substituted by Me, OMe or CO 2 Me have been measured under pseudo-first-order conditions. Rates are found to be affected not only by the nature of the substituent but by its position: e.g. a 2-OMe group causes retardation and a 3-OMe group a slight acceleration.