M. Hong
1981
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0
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Journal
Acta Chimica Sinica
Abstract
1,3-Bis (dimethylchlorosilyl)-propane was prepared by treating 1,3-bis-(trimethylsilyl) propane with sulphuric acid and then with ammonium chloride. In the presence of chloroplatinic acid six unsym-1, 3-bis(chlorosilyl)-propanes (A)were synthesized from the addition of metnyl chlorosilyl hydrides to allyldimethylchlorosilane. By the reaction of these compounds with ammonia or methylamine eighteen six-membered heterooyclic silicon-nitrogen compounds were obtained, the relation between the yields of the ammonolysis produots and the structures of the reactants was discussed.