F. Larsson, S. Lawesson
May 13, 1975
Citations
0
Influential Citations
6
Citations
Journal
Recueil des Travaux Chimiques des Pays-Bas
Abstract
Ethyl and phenyl chlorodithioformate have been reacted at −20°C with phenylmagnesium bromide and p-tolylmagnesium bromide to give substituted thioketones 4 in acceptable yields. The reaction between methyl chlorodithioformate and methylmagnesium iodide at −40°C gave dimethyl trithiocarbonate and 3,3,7,7-tetrakis(methylthio)-1,2,4,6-tetrathiepane-5-thione (8). When the reaction took place at 0°C other compounds also were isolated in small yields.