A. Zhdanov, V. Pakhomov, I. Arkhipov
Aug 1, 1967
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Journal
Russian Chemical Bulletin
Abstract
1. (2-Aminoethoxy)trimethylsilane reacts with chloromethylalkoxysilanes to form cyclic substitution products, with evolution of trimethylalkoxysilane. 2. The reaction of bis(2-aminoethoxy)dimethylsilane with chloromethylalkoxysilanes is accompanied by partial splitting off of the substituted methyl group from silicon. The N-methyl-substituted derivatives thus obtained react with the chloromethylalkoxysilanes to form cyclic substitution products, methylated at the nitrogen atom. 3. The authors have proposed a mechanism for the detachment of the substituted methyl group from the silicon atom.