Eduardo Dlaz, H. Barrios, B. Ortíz
Aug 1, 1989
Citations
0
Influential Citations
6
Citations
Journal
Magnetic Resonance in Chemistry
Abstract
The reaction of dibenzalcyclohexanone with hydroxylamine hydrochloride affords three compounds: the oxime of 2‐benzylidenecyclohexanone (2), 3‐phenyl‐7‐benzylidene‐3,3a,4,5,6,7‐hexahydro‐2,1‐benzisoxazole (3) and 3‐phenyl‐3,3a,4,5,6,7‐hexahydro‐2,1‐benzisoxazole‐7‐spiro‐2′‐(3′‐phenylaziridine) (4). Their structures were deduced by 2D NMR analysis. Single‐crystal x‐ray diffraction was used to confirm the structure and stereochemistry of 4. A possible mechanism for this reaction is proposed.