K. Shibata, Y. Itoh, N. Tokitoh
Dec 1, 1991
Citations
0
Influential Citations
4
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Reactions of dichlorotriphenylphosphorane with bis(trimethylsilyl) peroxide in the presence of some organic compounds have been found to give chlorinated products. Aromatic hydrocarbons bearing electron-donating substituents give the corresponding monochloroarenes, while an enol silyl ether is converted into α-chloro ketone. The mechanism is briefly discussed.