Fan Zhijie
1999
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Journal
Fine chemicals
Abstract
The reaction of isomaltulose with allyl alcohol catalysed by HCl gave no allyl isomaltuloside,but a mixture of the degradation by products 5 (α D glucopyranosyloxmethyl) 2 furancarboxaaldehyde (3a),allyl α,β D glucopyranoside (4a)and 5 (allyloxmethyl) 2 furancarboxaaldehyde(5).The mixture was acetylated to afford a mixture of compounds 5 (2,3,4,6 tetra O acetyl α D glucopyranosyloxmethyl) 2 furancarboxaaldehyde(3b),allyl 2,3,4,6 tetra O acetyl α,β D glucopyranoside (4b) and 5 (allyloxmethyl) 2 furancarboxaaldehyde (5).