Y. Ogibin, L. M. Il'ina, G. Nikishin
Dec 1, 1967
Citations
0
Influential Citations
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Citations
Journal
Russian Chemical Bulletin
Abstract
1. The free-radical addition of the methyl ester and nitrile of 3-methoxypropionic add to alkenes, initiated with ditert-butyl peroxide, leads to the formation of 1:1 adducts which consist of the methyl esters or nitriles of 2-alkyl-3-methoxy-, 3-alkyl-3-methoxy-, and 3-alkoxy substituted propionic acids. 2. The reaction is accompanied by the formation of a small quantity of by-products produced by the partialβ-dissociation of the CH2OCH2CH2COOCH3 and CH3OCHCH2COOCH3 radicals.