O. Kajimoto, H. Yamasaki, T. Fueno
Dec 1, 1979
Citations
0
Influential Citations
11
Citations
Journal
Chemical Physics Letters
Abstract
Abstract The reaction of excited oxygen atom, O( 1 D 2 ), with propylene has been studied under helium pressure up to 150 atm. The identified oxides and their limiting fractional yields are as follows: propylene oxide 0.22, propionaldehyde 0.22, acetone 0.11, allylalcohol 0.20, acrolein 0.02 and acetaldehyde 0.06. The mechanism of primary attack of O( 1 D 2 ) on olefin is inferred on the basis of these figures.