L. Gervits, K. Makarov, I. L. Knunyants
May 1, 1981
Citations
0
Influential Citations
4
Citations
Journal
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
Abstract
Conclusions1.Perfluoro-2-methyl-2-pentene reacts withα-oxides in the presence of CsF like perfluoroisobutylene. Olefins containing a perfluoro(dimethylpropyl)methyl group and cesium perfluoro-2-methyl-penten-3-olate are formed.2.The reaction of perfluoro-2-methyl-2-pentene with epichlorohydrin in the presence of CsP results in the formation of trans-1,1,1,7,7,8,8,9,9,9-decafluoro-2,6,6-tris(trifluoromethyl)-4-nonene, 2-fluoro-2-pentafluoroethyl-3,3-bis(trifluoromethyl)-5-[α,α-(uhydro-β,β-bis(trifluoromethyl)perfluoroamyl] tetrahydrofuran, and 2-H-perfluoro-2-methylpentane.3.The hexafluoropropylene dimer perfluoro-2-methyl-2-pentene is partially converted under the action of CsF into the thermodynamically most stable hexafluoropropylene trimer perfluoro-2,4-dimiethyl-3-heptene.