V. Snegirev, K. Makarov
Jul 10, 1986
Citations
0
Influential Citations
1
Citations
Journal
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
Abstract
ConclusionsPerfluoro-2-methyl-2-pentene reacts with alcohols to give either fluorine substitution products or addition products, depending on the amount of basic catalyst which is used. Alcohols containing branched substituents give another product in addition to those derived from substitution of a vinyl fluorine atom in perfluoro-2-methyl-2-pentene, namely isomeric vinyl ethers which are derivatives of perfluoro-2-methyl-1-pentene.Dehydrofluorination of the addition products, namely 2-hydro-3-alkoxyperfluoropentanes, leads in high yields to fluorine-containing allyl ethers containing terminal double bonds.