Y. Blum, Y. Becker, Y. Shvo
Dec 2, 1980
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0
Influential Citations
1
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract N -benzyloxypiperidine exhibits an unexpected type of reactivity toward Fe 2 (CO) 9 . Benzaldehyde and N -formylpiperidine are formed, most probably in a concerted manner, as revealed by deuterium-labeling experiments. Several mechanistic details of this reaction have been elucidated. The nature of the reaction contrasts with that of N -propyloxy- N -methylaniline, which upon treatment with Fe 2 (CO) 9 undergoes insertion of a CO group into the NO bond to generate a carbamate.