É. V. Kukharskaya, D. Andreev, V. Kolesova
Nov 1, 1958
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Journal
Russian Chemical Bulletin
Abstract
1. The reaction between trimethylsilylmethylmagnesium chloride and the ethyl esters of acetic and n-butyric acids proceeds normally, in the direction of the formation of tertiary alcohols, but is accompanied by 3 -decomposition, the splitting off from these alcohols in acid medium of one trimethylsilyl group. 2. When tertiary organosilicon alcohols containing a hydroxyl group on the β-carbon atom are dehydrated, unsaturated silicohydrocarbons are formed with a double bond in the β-position.