S. V. Serves, D. Sotiropoulos, P. V. Ioannou
Nov 1, 1995
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Journal
Phosphorus Sulfur and Silicon and The Related Elements
Abstract
Abstract Tris(trimethylsilyl) phosphite deoxygenates styrene epoxide and tritylglycidol. The same phosphite with glycidyl mesylate gave bis(trimethylsilyl) ester of 3-mesyl-2-trimethylsiloxypropylphosphonic acid by attack at the epoxide methylene carbon. The ester was not stable and reacted further intrarnolecularly. With glycidyl tosylate and glycidyl 3-nitrobenzenesulfonate, however, the reaction was more complicated and glyceryl 1,3-bis(arenesulfonate) was one of the products. With these activated glycidols deoxygenation and reduction of the nitro group were also observed.