R. F. Stockel
Aug 1, 1968
Citations
0
Influential Citations
11
Citations
Journal
Canadian Journal of Chemistry
Abstract
Dicyclohexylphosphine and diphenylphosphine react with 1,2-dichlorohexafluorocyclopentene to give almost exclusively the monoderivative via displacement of a vinylic chlorine atom. With the former phosphine a disubstituted derivative is also found. In addition to analytical values and infrared spectroscopic data, both 19F and 31P nuclear magnetic resonance spectra support the proposed structures.